FW: [Biochar] [CDR] Question about CDR and energy








 

 

Doc / Dr TLUD / Paul S. Anderson, PhD

         Email:  psanders@ilstu.edu       Skype:   paultlud

         Phone:  Office: 309-452-7072    Mobile & WhatsApp: 309-531-4434

Websites:    https://woodgas.com see Resources for biochar white paper and about RoCC kilns.  

                      https://drtlud.com see Quick Picks for TLUD stove technology.

                      https://capitalism21.org for societal reforms and free digital  novella “A Capitalist Carol”  with pages 88 – 94 about solving the world
crisis for clean cookstoves.

 

From: main@Biochar.groups.io <main@Biochar.groups.io&gt;
On Behalf Of Paul S Anderson via groups.io

Sent: Thursday, March 17, 2022 12:18 PM

To: Eelco Rohling <eelco.rohling@anu.edu.au&gt;; Peter Fiekowsky <pfieko@gmail.com&gt;

Cc: Ye Tao <tao@rowland.harvard.edu&gt;; H simmens <hsimmens@gmail.com&gt;; Carbon Dioxide Removal <carbondioxideremoval@googlegroups.com&gt;; healthy-planet-action-coalition <healthy-planet-action-coalition@googlegroups.com&gt;; main@Biochar.groups.io

Subject: Re: [Biochar] [CDR] Question about CDR and energy

 

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Dear Eelco and all,

 

I have been following this discussion, but from a rather different perspective.   My specialty is pyrolytic production of energy and biochar (I am subscribed to the CDR group and  Biochar group, but not to the healthy planet group, so please
forward).  (Background:  Retired prof. of Geography; PhD from Australian National University (Demography – migration studies – 1979).

 

Basically, I would like to have massive amounts of seaweeds (any types) so that the CO2 captured by the seaweed can be transformed for long-term sequestration as biochar.  I will gladly explain how to accomplish this (at sea or on shore),
but here I want to continue the discussion of accomplishing major growth of the organic material in the oceans.  A few comments and questions:

 

1.  Evidently the Sargasso Sea does not have much sargassum?   Calm waters and plenty of sunshine.  Could OIF work there?   Not enough nutrients? 

 

2.  Can the overabundant nutrients in the Gulf of Mexico near discharge of the Mississippi River be an appropriate nutrient source for the ocean plants?   Could OIF trigger massive biomass growth there?   If so, we could encircle it and
have continual harvesting for pyrolysis to yield biochar as a valuable product for enhancing soils while sequestering carbon.

 

3.  Is there anywhere in the world where massive growth of seaweeds/etc. could be grown for harvesting to make biochar?  No need to complete with other uses of macro-algae/kelp farming, etc.   We only want the  excess biomass.

 

My white paper “Climate Intervention with Biochar” was released back  in Dec. 2020, so it does not include my current thoughts on seaweed biochar.  My patented pyrolysis technology (for low cost and large volume) is called RoCC kilns; documents
about it are at my website.

 

Paul

 

Doc / Dr TLUD / Paul S. Anderson, PhD

         Email:  psanders@ilstu.edu       Skype:   paultlud

         Phone:  Office: 309-452-7072    Mobile & WhatsApp: 309-531-4434

Websites:   
https://woodgas.com
see Resources for biochar white paper and about RoCC kilns. 

                      https://drtlud.com
see Quick Picks about TLUD stove technology.

                      https://capitalism21.org
for societal reforms and free digital novella “A Capitalist Carol”  with pages 88 – 94 about solving the world crisis for clean cookstoves.

 

From: ‘Eelco Rohling’ via Carbon Dioxide Removal <CarbonDioxideRemoval@googlegroups.com>

Sent: Thursday, March 17, 2022 7:10 AM

To: Peter Fiekowsky <pfieko@gmail.com>

Cc: Ye Tao <tao@rowland.harvard.edu>; H simmens <hsimmens@gmail.com>; Carbon Dioxide Removal <carbondioxideremoval@googlegroups.com>;
healthy-planet-action-coalition <healthy-planet-action-coalition@googlegroups.com>

Subject: Re: [CDR] Question about CDR and energy

 

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Thanks for the details, Peter.

 

However, when you say “As you implied, and I’ll make explicit, some of the CO2 ends up as biocarbon (organic carbon), coming from photosynthesis, and some ends up as “dissolved CO2” or inorganic carbon. Chemically inorganic carbon is more
complicated than CO2, but starts as CO2 in the air, it dissolves into the water, like a soda water dispenser does, and eventually emerges out as CO2 again–like fizz from soda water,” you have quite some misconceptions in there.

 

Biocarbon in the ocean is a remarkably small pool. Where terrestrial living organic carbon standing stock amounts to some 600 GtC, this is only maybe 3 to 5 GtC in the ocean. The annual fluxes in and out of those living standing stocks
are not far removed from one another (both of the order of 60-90 GtC/y). This demonstrates that the ocean turnover (or residence time) of biological carbon is extremely rapid, and that it is much slower on land. We all know this in an anecdotal manner. Phytoplankton
(algae) live only briefly, while trees live very long.

 

The biological pump is the fraction of the living (and dying) marine biota that sinks below the photic layer and decomposes (is respired) there. Typically, only 1% or so of the biological production in the photic layer sinks into deeper
layers below the photic layer and is respired there. That is under nutrient-poor surface waters, where the ecosystem is “conditioned” to be highly efficient. Under nutrient-rich waters (upwelling regions), the sinking component can be greater, up to 25% or
so. That is because in these regions, the food web is less complicated and more wasteful (there’s food aplenty). 

 

All organic matter that decomposes drives CO2 addition into the dissolved inorganic carbon pool. So your assumption that the DIC is merely a result of the solubility pump is wrong. The DIC is “fed” by both the biological pump and the solution
pump.

 

The oceanic DIC pool today is some 39,000 GtC large. As you can see the organic carbon pool in the ocean pales into insignificance. But over time, the rapid-cycling organic pool and its small but steady loss that makes up the biological
pump does affect the DIC pool. It just takes tens of thousands of years, as Jelle wrote. 

 

Accelerating the biological pump with iron fertilisation may be possible, but it is effective only in so called High Nutrient Low Chlorophyll regions. Those conditions are not very common, but certain regions (e.g., larger parts of the
Southern Ocean) have such conditions and are therefore targets. As Tom Goreau has pointed out several times before, using any old iron is pretty inefficient. To have efficiency, the iron would need to be presented in a biologically available form. And we also
need to then focus on the next (micro-)nutrient that may run out, and Phosphate is of particular concern there. If that becomes limiting, it is a macronutrient which would be needed in much greater quantities than the micronutrient iron. 

So a limited experiment with a carefully prepared iron sample will work, but limitations arise from macronutrient shortage if/when we try to do iron fertilisation too rapidly and/or by too much.  In natural climate cycles it played a (limited)
role because the process was extended over many 10s of thousands of years. That is very different from going out and dumping a considerable portion of Australian dust in the Southern Ocean (incidentally, that arguably also would not be the most bioavailable
iron form).

 

Things are actually very complex and interwoven, and we cannot simplify it to the point of making a simple solution. If this is going to be part of the solution, then it will have to be by taking the complexity completely into account,
and addressing it in a well-balanced manner.

And that even ignores the fact that we may not know all the components that worked in the natural past. As Jelle says, there are serious suggestions around that whale poo played an important role. But that is not considered at all yet in
the studies. If that (or any other) missing component is a critical link in the chain of events, then we’re royally stuffed. We need to go out and study this matter, and if we get good programs set up, we may get to a sensible proposition in 5 years.

 

We cannot, and should not, do this in a trial and error manner. Past maverick experiments have set back the scientific progress massively, and as a result we still don’t have a complete assessment of the real potential of this method. Repeating
that sequence of event will just set back the potential implementation date even further. There are other CDR methods (and potentially also SRM methods) that are easier to oversee that we can implement earlier. OIF may be a very important one for CDR, but
only if we develop it in the right way. 

 

===

Prof. Eelco J. Rohling

(Ocean & Climate Change)

– 2012 Australian Laureate Fellow

– editor, Reviews of Geophysics

Research School of Earth Sciences

The Australian National University

Canberra, ACT 2601

Australia

Mobile: (+61) 434 667441

Tel. Office: (+61) 2 612 53857

e-mail: eelco.rohling@anu.edu.au

personal WebURL: http://www.highstand.org/erohling/ejrhome.htm

secondary email: eelco_rohling@me.com

 

On 17 Mar 2022, at 15:26, Peter Fiekowsky <pfieko@gmail.com> wrote:

 

Eelco-

Thank you for the corrections and clarifications. I apologize for assuming too much in my too short response. 

 

The bottom line was that there are CDR mechanisms that can remove a trillion tons of CO2 that require very little energy and can be done now–even while we’re still burning fossil fuel.  I think your well reasoned response confirms that.

 

I think most people on this list are aware that triggers are different from the mechanism. It is well accepted that orbital mechanics triggered ice ages. You implied and I’ll make explicit that orbital mechanics do not remove CO2 from the
atmosphere, neither do ice-albedo changes. It’s CO2 removal we’re interested in.

 

The mechanism for ice ages can be expressed a bit more clearly, so that readers can see how we might utilize those low energy mechanisms, at least until there is sufficient carbon free energy available for running DAC. I’ll explain this–since
it is not yet well known by many interested in CDR.

 

I think it’s well accepted from ice core data that CO2 levels during the ice ages go down roughly the same amount as we’ve raised CO2 in the last 100 years, about 130 ppm. This corresponds to roughly a trillion tons of CO2 moved from the
atmosphere into the ocean going into the ice age; and then released back into the air typically 30,000 years later as the ice age ends. As you implied, and I’ll make explicit, some of the CO2 ends up as biocarbon (organic carbon), coming from photosynthesis,
and some ends up as “dissolved CO2” or inorganic carbon. Chemically inorganic carbon is more complicated than CO2, but starts as CO2 in the air, it dissolves into the water, like a soda water dispenser does, and eventually emerges out as CO2 again–like fizz
from soda water.

 

I think you’re arguing about how much of the trillion tons of CO2 stored in the ocean during ice ages is stored as organic versus inorganic carbon. This number is debated, and it may have varied in different parts of the ocean. So let’s
agree that it’s unknown, and perhaps unknowable since there is no fossil record from the midocean.

 

Although the ratio is unknown, there is decent evidence, from John Martin and many following him, that a large fraction was biocarbon originating from phytoplankton (plants) doing photosynthesis near the ocean surface. This photosynthesis
has been shown to be increased greatly by adding miniscule amounts of iron–about one milligram (1/1000 of a teaspoon) per square meter each year in many parts of the ocean. Thus the name ocean iron fertilization.

 

You may be arguing that 90% of the carbon was inorganic (“dissolved CO2”), not biocarbon. That might be true, and if so, that inorganic carbon phenomenon can be duplicated by suitable upwelling or downwelling, which also requires very little
energy–a few square meters of solar cells.

 

Regarding the synthetic limestone (CaCO3) from CaO and CO2, this reaction is exothermic, so the only energy required for pumping fluids, maybe $1 of electricity per ton CO2 sequestered.

 

Again, I apologize for leaving too much unsaid the first time.

Peter

 

On Wed, Mar 16, 2022 at 3:55 PM Eelco Rohling <eelco.rohling@anu.edu.au> wrote:

I am all for the start with CDR as soon as possible, but we should be careful to use gross (and wrong) generalisations when we want to make a point. OIF is not how nature produces ice ages.

Ice ages are “produced” in response to orbital forcing cycles. These are small on global average, but have considerable seasonal and spatial gradients. Then, a series of feedbacks is started. Key ones are ice-albedo feedback, and carbon
cycle feedbacks. Ice albedo should be obvious. Carbon cycle feedbacks, however, are not. They are not simply, or merely, or even dominantly OIF. Elements at play: (1) the solubility pump brings more carbon into cooling surface water and then deep water (through
deep-water formation). (2) changes in ocean circulation (and upwelling/outgassing) also come into play, creating expansion of deep-water masses that have more accumulated DIC. (3) the biological pump (which Peter equates to OIF, but it’s much more complicated
than just that process) plays a role in accumulation of DIC in the deep-water masses mentioned under 2. 

Overall, the total biological pump effect can be estimated from paired B/Ca (= carbonate ion proxy) and Cd/Ca (= nutrient proxy) analyses, and has been found to be about 50% if I’m not mistaken, during the last glacial maximum. But, as
said before, much of that is not due to OIF, but due to a whole host of processes that favour net DIC accumulation in the deep sea. Let’s assume that OIF makes up half of that amount. That would mean that 25% of the carbon-cycle influence on ice ages is due
to OIF, and carbon cycle (CO2) impact on ice ages is at best 30-50% of the total forcing/feedback story. So, in a rough approximation, OIF may have a 8-13% contribution in “producing” ice ages.

 

Gross generalisation won’t help when you want to rail against the opinions of scientists. It only gives them a means to push tyour argument aside. 

Again, I am all for a big simultaneous push on CDR along with net zero emissions, but we need to be more careful in our messaging of “facts”.

===

Prof. Eelco J. Rohling

(Ocean & Climate Change)

– 2012 Australian Laureate Fellow

– editor, Reviews of Geophysics

Research School of Earth Sciences

The Australian National University

Canberra, ACT 2601

Australia

Mobile: (+61) 434 667441

Tel. Office: (+61) 2 612 53857

e-mail: eelco.rohling@anu.edu.au

<PastedGraphic-1.tiff>

personal WebURL: http://www.highstand.org/erohling/ejrhome.htm

secondary email: eelco_rohling@me.com

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On 17 Mar 2022, at 08:09 , Peter Fiekowsky <pfieko@gmail.com> wrote:

 

CDR using synthetic limestone (Blue Planet Systems) and OIF (how nature produces ice ages) don’t require significant energy. Although the peer reviewed literature doesn’t entertain many approaches to scaling them yet, there is no compelling
reason that they can’t be scaled while we’re transitioning to clean energy.

 

Peter

 

On Wed, Mar 16, 2022 at 1:57 PM Ye Tao <tao@rowland.harvard.edu> wrote:

The comment from the climate scientists is mostly correct, except that existing CDR is fundamentally inefficient.  A more correct phrasing is therefore:

"Effective CDR will require energy. That energy needs to be zero-carbon to make CDR relevant. Hence the need to decarbonize the energy sector first"

Ye

On 3/16/2022 4:43 PM, H simmens wrote:

I am on Twitter now engaging in a conversation with three well-known climate scientists who responded as follows when I argued that we need to start large scale CDR now and not wait to mid century:

 

"Effective CDR will require energy. That energy needs to be zero carbon to make CDR efficient. Hence the need to decarbonize the energy sector first"

 

How would you suggest I respond?

 

Herb

 

 

 

 

Herb Simmens

Author A Climate Vocabulary of the Future

@herbsimmens

 

 

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 Founder and Chairman Emeritus

Restoring a proven safe climate (300 ppm CO2 by 2050) for the flourishing of humanity. Climate
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